Product ID:SUPER SHOCK-IT
MSDS Date:06/15/1998
FSC:6810
NIIN:00-238-8115
Status Code:A
MSDS Number: CKBRF

Emergency Phone: 304-843-1300

Info Phone: 304-843-1300

Preparer: R. KENNETH LEE

Cage: 47695

Telephone: 1-800-245-2974 (CAL HYPO)

Cage: 47695

CALCIUM HYPOCHLORITE

CAS: 7778-54-3

RTECS: NH3485000

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF CALCIUM HYPOCHLORITE
DUST & DEPOSITION OF PRATICLES IN THE RESPIRATORY TRACT CAN LEAD TO
IRRITATION OF THE TISSUE & CAUSE A VARIETY OF EFFECTS; UPPER
RESPIRATORY TRACT IRRITATION, NASAL CONGESTION, COUGHING, SORE
THROAT, LARYNGITIS & SHORTNESS OF BREATH.EYE: CALCIUM HYPROCHLORITE
IS CORROSIVE TO THE EYES, EVEN A MINUTE AMOUNT FOR A SHORT
DURATION, CAN CAUSE SEVERE IRRITATION & EVEN BLINDNESS. SKIN:
CONTACT WITH THE SKIN MAY CAUSE SEVERE IRRITATION, BURNS, OR TISSUE
DESTRUCTION. INGESTION:CALCIUM HYPO-CHLORITE, IF SWALLOWED, CAUSES
SEVERE BURNS TO THE DIGESTIVE TRACT & CAN BE FAT AL.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED AS A
CARCINOGEN OR SUSPECTED CARCINOGEN BY NTP, IARC, OR OSHA.
Effects of Overexposure:DO NOT SWALLOW. SWALLOWING MAY CAUSE INJURY OR
DEATH. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. MAY CAUSE
BURNS. AVOID BREATHING DUST. IRRITATING TO NOSE AND THROAT.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE/SKIN: IMMEDIATELY
FLUSH EYES & SKI N WITH PLENTY OF WATER(SOAP & WATER FOR SKIN)FOR
AT LEAST 15 MINUTES, WHILE REMOVING CONTAMINATED CLOTHING & SHOES.
FOR EYE CONTACT, GET IMMEDIATE MEDICAL ATTENTION. IF SKIN
IRRITATION OCCURS, GET MED ICAL ATTENTION. INGESTION: IF SWALLOWED,
GIVE AT LEAST 3-4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. DO
NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING PERSON.
GET MEDICAL ATTENTION.

Flash Point:NONE
Extinguishing Media:WATER ONLY. SMOTHERING INEFFECTIVE-PRODUCT SUPPLIES
OWN OXYGEN.
Fire Fighting Procedures:PRODUCT DECOMPOSES AT 180 C RELEASING OXYGEN
GAS. CONTAINER MAY RUPTURE. FIRE-FIGHTERS MUST WEAR NIOSH APPROVED,
PRESSURE DEMAND, SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE
PIECE FOR POSSIBLE E XPOSURE TO HAZARDOUS GASES.
Unusual Fire/Explosion Hazard:DANGER! STRONG OXIDIZING AGENT! MIX ONLY
WITH WATER. CONTAMINATION MAY CAUSE FIRE OR EXPLOSION. DO NOT ADD
THIS PRODUCT TO ANY DISPENSING DEVICE CONTAINING REMNANTS OF ANY
OTHER PRODUCT.

Spill Release Procedures:USE EXTREME CAUTION IN HANDLING SPILLED
MATERIAL. CONTAMINATION WITH ORGANIC OR COMBUST-BLE MATERIAL MAY
CAUSE FIRE OR VIOLENT DECOMPOSITION. IF FIRE OR DECOMPOSITION
OCCURS IN AREA OF SPILL, IMMEDIAT ELY DOUSE WITH PLENTY OF WATER.
OTHERWISE, SWEEP UP ALL VISIBLE MATERIAL USING A CLEAN, DRY SHOVEL&
BROOM AND DISSOLVE MATERIAL IN WATER.
Neutralizing Agent:HYDROGEN PEROXIDE (ONE PINT OF 35% HYDROGEN PEROXIDE
PER POUND OF CALCIUM HYPOCHLORITE).

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
PLACE AWAY FROM HEAT & SOURCES OF IGNITION. KEEP IN ORIGINAL
CONTAINER. ADD THIS PRODUCT ONLY TO WATER. MAY CAUSE FIRE OR
EXPLOSION IF MIXED WITH OTHER CHEMICALS. RESIDUAL MATERIAL IN
EMPTY CONTAINER CAN REACT & CAUSE FIRE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. MAY CAUSE FIRE OR
EXPLOSION IF MIXED WITH OTHER CHEMICALS. DO NOT CONTAMINATE WATER,
FOOD OR FEED BY STORAGE OR DISPOSAL. DO NOT CONTAMINATE WATER, FOOD
OR FEED BY STORA GE OR DISPOSAL.

Respiratory Protection:IF DUSTY CONDITIONS ARE ENCOUNTERED, USE NIOSH
APPROVED RESPIRATOR WITH ACID GAS CARTRIDGE AND DUST PREFILTER. THE
RESPIRATORY USE LIMITATIONS MADE BY NIOSH OR THE MANUFACTURER MUST
BE OBSERVED. RESPI RATORY PROTECTION PROGRAMS MUST BE IN ACCORDANCE
WITH 29 CFR 1910.134.
Ventilation:NONE REQUIRED UNNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Protective Gloves:NATURAL OR SYNTHETIC RUBBER.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:BOOTS, APRONS, OR CHEMCIAL SUITS SHOULD BE
USED WHEN NECESSARY TO PREVENT SKIN CONTACT. PERSONAL PROTECTIVE
CLOTHING AND USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH 29 CFR
1910.132.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.

HCC:D1
Boiling Pt:B.P. Text:DECOMPOSES
Decomp Temp:=180.C, 356.F
pH:ALKALINE
Solubility in Water:217 G/L @ 27 C
Appearance and Odor:WHITE POWDER, SLIGHT CHLORINE ODOR.

Stability Indicator/Materials to Avoid:YES
CONTAMINATION. EXCESSIVE HEAT ABOVE 177 C, ACIDS, COMBUSTIBLE
MATERIALS. ORGANICS. REDUCING AGENTS.
Stability Condition to Avoid:UNSTABLE ABOVE 177 C.
Hazardous Decomposition Products:ACID OR AMMONIA CONTAMINATION WILL
RELEASE TOXIC GASES. EXCESSIVE HEAT WILL CAUSE DECOMPOSITION
RESULTING IN THE RELEASE OF OXYGEN AND CHLORINE GAS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:SPILLED MATERIAL THAT HAS BEEN SWEPT UP AND
DISSOLVED IN WATER SHOULD BE USED IMMEDIATELY IN THE NORMAL
APPLICATION FOR WHICH THIS PRODUCT IS BEING USED. IFTHIS IS NOT
POSSIBLE, CAREFULLY NEUTRALIZE D ISSOVED MATERIAL BY ADDING
HYDROGEN PEROXIDE THEN DILUTE THE NEAUTRALIZED MATERIAL WITH PLENTY
OF WA TER AND FLUSH TO SEWER.

Toxicological Information:ACUTE INHALATION LC50: (RAT) NO MORTALITY AT
3.5 MG/L (1 HR) IRRITATING. ACUTE DERMAL LD50: (RABBIT) >1000
MG/KG. SLIGHT TO VERY LOW TOXICITY. SKIN IRRITATION: CAUSES BURNS.
EYE IRRITATION: CAUSES BUR NS. ACUTE ORAL LD50: (RAT) 850 MG/KG.
SLIGHT TO VERY LOW TOXICITY. CHRONIC EFFECTS CARCINOGENICITY: THIS
PRODUCT IS NOT LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY
NTP, IARC OR OSHA. MEDICAL CON DITIONS AGGRAVATED: NONE KNOWN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:HIGHLY TOXIC TO AQUATIC LIFE. 0.088 MG/L (BLUEGILL) 96-HR
LC50.

Transport Information:US DOT DESCRIPTION: SHIPPING NAME: CALCIUM
HYPOCHLORITE, HYDRATED. HAZARD CLASS: 5.1 (OXIDIZER).
IDENTIFICATION NUMBER: UN2880. PACKING GROUP: II. REPORTABLE
QUANTITY: 10 LBS/4.5 KG.

SARA Title III Information:SECTION 311/312: ACUTE HEALTH HAZARD,
REACTIVE, FIRE HAZARD. SECTION 313: NOT LISTED. SECTION 302: NOT
LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE.
Federal Regulatory Information:USA TSCA: THIS PRODUCT IS LISTED ON THE
TSCA INVENTORY. CERCLA HAZARDOUS SUBSTANCE: LISTED IN TABLE 302.4
OF 40 CFR PART 302 AS A HAZARDOUS SUBSTANCE WITH A REPORTABLE
QUANTITY (RQ) OF 10 POUNDS. RELE ASES TO AIR, LAND & WATER WHICH
EXCEED THE RQ MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER,
800-424-8802. FIFRA: THIS PRODUCT IS REGISTERED WITH EPA AS A
PESTICIDE. RCRA: WASTE CALCIUM HYPOCHLORIT E & CONTAMIANTED
SOILS/MATERIALS FROM SPILL CLEANUP ARE D001 HAZARDOUS WASTE AS PER
40 CFR 261.21 (A )(4) AND MUST BE DISPOSED OF ACCORDINGLY UNDER
RCRA.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.